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mole fraction : ウィキペディア英語版
mole fraction
In chemistry, the mole fraction or molar fraction (x_i) is defined as the amount of a constituent (expressed in moles), n_i, divided by the total amount of all constituents in a mixture, n_:
:x_i = \frac^ n_i = n_ ; \; \sum_^ x_i = 1
The same concept expressed with a denominator of 100 is the mole percent or molar percentage or molar proportion (mol%).
The mole fraction is also called the amount fraction.〔 It is identical to the number fraction, which is defined as the number of molecules of a constituent N_i divided by the total number of all molecules N_. The mole fraction is sometimes denoted by the lowercase Greek letter ''\chi'' (''chi'') instead of a Roman x. For mixtures of gases, IUPAC recommends the letter y.〔
The National Institute of Standards and Technology of the United States prefers the term amount-of-substance fraction over mole fraction because it does not contain the name of the unit mole.
Whereas mole fraction is a ratio of moles to moles, molar concentration is a ratio of moles to volume.
The mole fraction is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and volume fraction (percentage by volume, vol%) are others.
==Properties==
Mole fraction is used very frequently in the construction of phase diagrams. It has a number of advantages:
* it is not temperature dependent (such as molar concentration) and does not require knowledge of the densities of the phase(s) involved
* a mixture of known mole fraction can be prepared by weighing off the appropriate masses of the constituents
* the measure is ''symmetric'': in the mole fractions x=0.1 and x=0.9, the roles of 'solvent' and 'solute' are reversed.
* In a mixture of ideal gases, the mole fraction can be expressed as the ratio of partial pressure to total pressure of the mixture

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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